250163-87-2Relevant academic research and scientific papers
Organometallic mediated radical polymerization of vinyl acetate using bis(imino)pyridine vanadium trichloride complexes
Perry, Mitchell R.,Allan, Laura E. N.,Decken, Andreas,Shaver, Michael P.
, p. 9157 - 9165 (2013/07/27)
The synthesis and characterization of one novel proligand and six novel vanadium(iii) trichloride complexes is described. The controlled radical polymerization activity towards vinyl acetate of these, and eight other bis(imino)pyridine vanadium trichlorid
Homogeneous Dimerization Catalysts Based on Vanadium
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Page/Page column 2; 5, (2011/04/18)
A series of new bis(imino)pyridine vanadium(III) complexes was synthesized according to formula: They were tested for the homogeneous catalytic dimerization of propylene after activation with MAO and showed excellent selectivity for dimerization. The catalysts can be used with or without PPh3 as an additive to produce ≧80% dimerized alkenes.
