250355-70-5

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 250355-69-2 Acetic acid (4R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-(2-hydroxy-ethyl)-tetrahydro-pyran-2-yl ester 
• 250355-67-0 (4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-triethylsilanyloxy-nona-1,8-diene 
• 250355-68-1 Acetic acid (4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-(2-oxo-ethyl)-tetrahydro-pyran-2-yl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 135943-86-1 (4S,6S)-nona-1,8-diene-4,6-diol 
• 250355-66-9 (4S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-nona-1,8-dien-4-ol 

Downstream Products

• 250355-71-6 {4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-acetaldehyde 
• 250355-75-0 (2S,6R)-2-{(2R,4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-ylmethyl}-6-[2-(4-methoxy-benzyloxymethyl)-oxazol-4-yl]-[1,3]dioxan-4-one 

Relevant academic research and scientific papers

Phorboxazole synthetic studies. 1. Construction of a C(3-19) subtarget exploiting an extension of the Petasis-Ferrier rearrangement

(equation presented) In this, the first of two Letters, we outline our overall strategy for the total synthesis of phorboxazoles A (1) and B (2), rare oxazole-containing macrolides possessing extraordinary antimitotic activity, and describe the assembly o