250611-13-3

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Product Name: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
Synonyms: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINIUM(III) CHLORIDE;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE;Cyclohexanediaminobisdibutylsalicyliden;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]aluminum(III)chloride;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride;(1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluMinuM(III) chloride,98% (R,R)-Salen-Al;(R,R)Salen AI
CAS NO:250611-13-3
Molecular Formula: C36H52AlClN2O2
Molecular Weight: 607.24
EINECS: N/A
Product Categories: Jacobsen Metal
Mol File: 250611-13-3.mol
Article Data: 0

Chemical Properties

Melting Point: 250-255 °C(lit.)
Boiling Point: N/A
Flash Point: N/A
Appearance: yellow/Powder
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE(CAS DataBase Reference)
NIST Chemistry Reference: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE(250611-13-3)
EPA Substance Registry System: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE(250611-13-3)

Safety Data

Hazard Codes: Xn
Statements: 20/21/22
Safety Statements: 26-36
WGK Germany: 3
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 250611-13-3(Hazardous Substances Data)

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(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis-(3,5-di-tert-butylsalicylidene)]aluminum(III)chloride
Cas No: 250611-13-3
USD $ 3.0-3.0 / Kilogram
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Dayang Chem (Hangzhou) Co.,Ltd.
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Chinese Standard CAS 250611-13-3 with competitive price
Cas No: 250611-13-3
USD $ 146.0-176.0 / Gram
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1000 Kilogram/Day
Zhuozhou Wenxi import and Export Co., Ltd
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(R,R)-N,N"-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Cas No: 250611-13-3
USD $ 1173.0-1173.0 / Gram
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Baoji Guokang Healthchem co.,ltd
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(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Cas No: 250611-13-3
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Hangzhou J&H Chemical Co., Ltd.
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(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
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GIHI CHEMICALS CO.,LIMITED
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
Cas No: 250611-13-3
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Henan Allgreen Chemical Co.,Ltd
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
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BOC Sciences
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(1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluMinuM(III) chloride
Cas No: 250611-13-3
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Antimex Chemical Limied
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
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Hangzhou Fandachem Co.,Ltd
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
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Chemsigma International Co.,Ltd.
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250611-13-3 Usage

Reaction

Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling. Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis. Catalyst used for the asymmetric hydrocyanation of nitroolefins. Catalyst used in the reaction of epoxides with heterocumulenes.

Uses

Catalyst for:Asymmetric iodolactonizationsCyanosilylation reactionsPhospho-aldol catalysis

Check Digit Verification of cas no

The CAS Registry Mumber 250611-13-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,5,0,6,1 and 1 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 250611-13:
(8*2)+(7*5)+(6*0)+(5*6)+(4*1)+(3*1)+(2*1)+(1*3)=93
93 % 10 = 3
So 250611-13-3 is a valid CAS Registry Number.

InChI:InChI=1/C36H54N2O2.Al.3ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;3*1H/q;+3;;;/p-3/b37-21+,38-22+;;;;/t29-,30-;;;;/m1..../s1

250611-13-3 Well-known Company Product Price

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Aldrich
(531960) (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride
250611-13-3
531960-1G
699.66CNY
Detail

250611-13-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name	(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE

1.2 Other means of identification

Product number	-
Other names	-

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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