25066-36-8

Basic information

• Product Name: cyclohexyl methyl carbonate
• Synonyms: carbonic acid, cyclohexyl methyl ester; Cyclohexyl methyl carbonate
• CAS NO: 25066-36-8
• Molecular Formula: C₈H₁₄O₃
• Molecular Weight: 158.195
• Mol File: 25066-36-8.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 240.3°C at 760 mmHg
• Flash Point: 102.1°C
• Density: 1.03g/cm³
• Vapor Pressure: 0.0382mmHg at 25°C
• Refractive Index: 1.444
• CAS DataBase Reference: cyclohexyl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl methyl carbonate(25066-36-8)
• EPA Substance Registry System: cyclohexyl methyl carbonate(25066-36-8)

Safety Data

• Hazardous Substances Data: 25066-36-8(Hazardous Substances Data)

Upstream product

• 79-22-1 methyl chloroformate 
• 108-93-0 cyclohexanol 
• 124-38-9 carbon dioxide 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 
• 108-94-1 cyclohexanone 
• 616-38-6 carbonic acid dimethyl ester 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Light-induced synthesis of unsymmetrical organic carbonates from alcohols, methanol and CO2under ambient conditions

The present work describes the first visible light-assisted, metal-free and organic base 1,1,3,3-tetramethyl guanidine (TMG) mediated synthesis of unsymmetrical methyl aryl/alkyl carbonates from the reaction of alcohols, methanol, and CO2 in high to excel

Synthesis of non-symmetrical alkyl carbonates from alcohols and DMC over the nanocrystalline ZSM-5 zeolite

A novel heterogeneous acid (nanocrystalline ZSM-5) catalyzed carboxymethylation of alcohols to non-symmetrical alkyl carbonates using DMC has been realized. Nanocrystalline ZSM-5 (NZSM-5) with a crystal size of 20-30 nm was synthesized by hydrothermal crystallization. The synthesized NZSM-5 was verified by X-ray diffraction, Fourier transformation infrared spectroscopy and solid state NMR. The morphology of NZSM-5 was confirmed by transmission electron microscopy and scanning electron microscopy, which revealed the formation of aggregates of the zeolite (100-200 nm) made by the nano-sized (20-30 nm) NZSM-5 particle packing. The physicochemical properties of NZSM-5 were measured by nitrogen adsorption and temperature programmed desorption of ammonia, which indicate the surface area of 465 m2 g-1 and the acidity of 0.936 mmol g-1. The present protocol provides an attractive approach to a variety of non-symmetrical alkyl carbonates in high yields. The catalyst was efficiently recycled for up to 5 consecutive cycles. This method broadens the series of possible utilization for DMC in green chemistry.

ZINC COMPLEX

A zinc complex characterized in exhibiting an octahedral structure and being configured from repeating units represented by general formula (I): wherein L represents a linker region, and R1 represents a C1-4 alkyl group, which can have a halogen atom.