2510-74-9

Basic information

• Product Name: Benzene, 1,1'-(1Z)-1,2-ethenediylbis[4-chloro-
• CAS NO: 2510-74-9
• Molecular Formula: C14H10Cl2
• Molecular Weight: 249.139
• Mol File: 2510-74-9.mol
• Article Data: 103

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1Z)-1,2-ethenediylbis[4-chloro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1Z)-1,2-ethenediylbis[4-chloro-(2510-74-9)
• EPA Substance Registry System: Benzene, 1,1'-(1Z)-1,2-ethenediylbis[4-chloro-(2510-74-9)

Safety Data

• Hazardous Substances Data: 2510-74-9(Hazardous Substances Data)

Upstream product

• 23566-17-8 bis(4-chlorobenzyl)disulfide 
• 10311-79-2 1-chloro-1,2-bis(p-chlorophenyl)ethane 
• 6966-45-6 4-chlorobenzylsulfonyl chloride 
• 74-85-1 ethene 
• 122-01-0 4-chloro-benzoyl chloride 
• 13940-94-8 (4-chlorophenyl)dichloromethane 
• 2642-82-2 2,2-bis(p-chlorophenyl)ethanol 
• 43170-85-0 sodium (4-C₆H₄ClCH₂)(thiolate) 
• 37580-81-7 1,2-bis(4-chlorophenyl)-1,2-ethandiol 
• 1820-42-4 bis(4-chlorophenyl)acetylene 
• 50-29-3 p,p'-DDT 
• 72-54-8 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethane 
• 46175-04-6 sodium (4-chlorophenyl)(hydroxy)methanesulfonate 
• 51229-56-2 1-chloro-4-((phenylsulfonyl)methyl)benzene 

Downstream Products

• 62006-50-2 trans-1,2-bis-(p-chlorophenyl)ethane oxide 
• 79183-98-5 1,2-dibromo-1,2-di-(p-chlorophenyl)-ethane 
• 16740-47-9 meso-4.4'.α.α'-tetrachloro-bibenzyl 
• 16740-47-9 racem.-4.4'.α.α'-tetrachloro-bibenzyl 
• 5216-37-5 (E)-4,4'-dicyanostilbene 
• 2510-74-9 (E)-1,2-di(4-chlorophenyl)ethene 
• 130272-00-3 8-Methoxy-3,4,5,7-tetrahydro-1,3,7-trimethyl-anti-10,syn-11-bis(4-chlorphenyl)-4,5-ethano-1H-purin-2,6-dion 
• 130168-08-0 8-Methoxy-3,4,5,7-tetrahydro-1,3,7-trimethyl-syn-10,anti-11-bis(4-chlorphenyl)-4,5-ethano-1H-purin-2,6-dion 
• 5216-35-3 1,2-bis(4-chlorophenyl)ethane 
• 62006-50-2 cis-4,4'-dichloro-α,α'-epoxy bibenzyl 
• 37580-81-7 (syn)-1,2-bis(4-chlorophenyl)ethane-1,2-diol 
• 1454309-38-6 2-bromo-6-chloro-1-(4-chlorophenyl)-1H-indene 

Relevant articles and documents

Efficient preparation method of symmetric diarylethene compound

The invention belongs to the technical field of fine chemicals and related chemistry, and provides an efficient preparation method of a symmetric diarylethene compound. The method comprises the following steps: with halomethyl-containing aromatic hydrocarbon and derivatives thereof as raw materials, conducting reacting at 100 DEG C for 12 hours in the presence of a catalyst, alkali, additives andan anhydrous organic solvent so as to obtain the corresponding diarylethene compound with symmetry. The method has the beneficial effects that no transition metal reaction exists, reaction conditionsare mild, operation is simple and convenient, the possibility of industrialization is realized, and the diarylethene compound is obtained at high yield; and the diarylethene compound synthesized by using the method can be further functionalized to obtain various compounds, and is applied to development and research of natural products, functional materials and fine chemicals.

Photocatalyst-free visible light promoted: E → Z isomerization of alkenes

A simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed. A variety of (Z)-alkenes can be prepared in the presence of visible light, without any additional photocatalyst. This protocol features photocatalyst-free conditions, which are mild, tolerant, and operationally simple, and is easy to implement.

A Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Alkynes to (E)-Alkenes with Ethanol

Four Ru(II)-NC complexes were tested as catalysts for semihydrogenation of internal alkynes to (E)-alkenes with ethanol, and the complex {(C5H4N)(C6H4)}RuCl(CO)(PPh3)2 (1a) showed the highest activity. The reactions proceeded well with 1 mol % catalyst loading and 0.1 equiv of t-BuONa at 110 °C for 1 h, and 32 alkenes were synthesized with excellent E:Z selectivity. This is the first ruthenium-catalyzed semihydrogenation of internal alkynes to (E)-alkenes using ethanol as the hydrogen donor.