25105-16-2Relevant academic research and scientific papers
Chemistry of Germanium Atoms. II. Reactions of Thermally Evaporated Germanium Vapor with Organic Halides
Mochida, Kunio,Tashiro, Kumiko,Yoshida, Yasuhiro,Mizuno, Yasuhisa
, p. 1247 - 1250 (2007/10/02)
Thermally generated germanium atoms were found to react with organic halides by insertion into carbon-halogen bonds.The resulting germylenes abstracted halogens from organic halides to form trihalogermyl derivatives.Tetrahalogermanes were also formed by t
Chemistry of Germanium Atoms. IV. A New Method for Preparation of Organogermanium Halides by Co-condensation of Germanium Vapor with Tetrahydrofuran
Mochida, Kunio,Nakai, Yuko,Shiota, Shigeru
, p. 3002 - 3004 (2007/10/02)
Germanium vapor (atom) when co-condensated with THF at 77 deg K was found to be reactive toward organic halides.Several organogermanium halides were prepared by the addition of organic halides to the resultant germanium atom-THF slurry at ambient temperatures.
The Reaction of Germanium Atoms with Organic Halides
Mochida, Kunio,Tashiro, Kumiko
, p. 1105 - 1108 (2007/10/02)
Co-condensation of thermally evaporated germanium vapor with organic halides yields a mixture of trihalogermyl derivatives and tetrahalogermanes as major products.The nature of these reactions is discussed.
