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Tris[2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl]phosphane, also known as C6F5P(C6F5)3, is a phosphorus-containing organometallic compound with a unique structure. It consists of a central phosphorus atom bonded to three identical tris(2,3,5,6-tetrafluoro-4-trifluoromethyl)phenyl ligands. tris[2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl]phosphane is characterized by its high thermal stability, low reactivity, and strong electron-withdrawing properties due to the presence of multiple fluorine atoms. It is primarily used as a ligand in transition metal complexes, particularly in the field of homogeneous catalysis, where it can enhance the catalytic activity and selectivity of various reactions. Additionally, its strong electron-withdrawing nature makes it a valuable building block for the synthesis of other organophosphorus compounds with potential applications in materials science and pharmaceuticals.

25147-72-2

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25147-72-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 25147-72-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,5,1,4 and 7 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 25147-72:
(7*2)+(6*5)+(5*1)+(4*4)+(3*7)+(2*7)+(1*2)=102
102 % 10 = 2
So 25147-72-2 is a valid CAS Registry Number.

25147-72-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name tris[2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl]phosphane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

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More Details:25147-72-2 SDS

25147-72-2Relevant academic research and scientific papers

Structural and electronic properties of tris(4-trifluoromethyltetrafluorophenyl)phosphine

Saunders, Graham C.

, p. 15 - 20 (2015/09/22)

Theoretical calculations on tris(4-trifluoromethyltetrafluorophenyl)phosphine, 1, and spectroscopic studies of its complexes, trans-[PtCl2{P(C6F4CF3-4)3}2], 3, and trans-[RhCl(CO){P(C6F4CF3-4)3}2], 4, indicate that it is a poorer σ donor than tris(pentafluorophenyl)phosphine. The structures of 1, 3 and 4 have been determined by single crystal X-ray diffraction, and indicate that the cone angle of 1 is the same as that of tris(pentafluorophenyl)phosphine.

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