25149-72-8

Upstream product

• 7439-93-2 lithium 
• 22702-72-3 1,1,2,2-tetramethyl-1,2-diphenyldigermane 
• 22702-76-7 phenyldimethylchlorogermane 

Downstream Products

• 119795-95-8 1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane 
• 119796-01-9 2,3,3,5-tetramethyl-2,5-diphenyl-3-sila-2,5-digermahexane 
• 119795-99-2 1-chloro-2,2,3-trimethyl-3-phenyl-2,3-digermabutane 
• 119796-04-2 (CH₃)2Ge(Ge(CH₃)2(C₆H₅))CH₂Ge(CH₃)2(C₆H₅) 
• 142103-23-9 C₆H₅Ge(CH₃)2Si(CH₃)2H 
• 217434-08-7 2-(dimethylphenylgermyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 91076-08-3 bis(dimethylphenylsilyl)zinc 
• 205485-41-2 bis(dimethylphenylgermyl)methylsilane 
• 55321-81-8 phenyldimethylgermyl 

Relevant academic research and scientific papers

Reaction of chloro(chloromethyl)dimethylsilane and -germane with group 14 element nucleophiles

Reaction of chloro(chloromethyl)dimethylsilane (1) or -germane (2) with group 14 element nucleophiles, R3M′Li (3, M′ = Si, Ge, and Sn), was examined to prepare R3M′-MMe2-CH2-Cl compounds (4, M = Si; 5, M = Ge).

Laser Photolysis and CIDEP Studies of the Formation of Phenyl-Substituted Group 4B Element (Silicon, Germanium, and Tin)-Centered Radicals in Direct Photoejection of the Group 4B Element-Centered Anions

Phenyl-substituted group 4B element-centered radicals generated by the direct photoejection from the group 4B element-centered anions were observed by laser photolysis at room temperature.In order to claify the mechanism of this process, CIDEP study of the photolysis of the group 4B element-centered anions was carried out at 77 and 4.2 K.From the emissive patterns observed for the germyl and stannyl anions after the excitation by a pluse laser, the photoejection reactions were most probably considered to occur from triplet anions.