251644-52-7

Basic information

• Product Name: Silane, trimethyl[3-phenyl-1-[(1R)-1-phenylethoxy]propoxy]-
• CAS NO: 251644-52-7
• Molecular Formula: C20H28O2Si
• Molecular Weight: 328.527
• Mol File: 251644-52-7.mol

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[3-phenyl-1-[(1R)-1-phenylethoxy]propoxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[3-phenyl-1-[(1R)-1-phenylethoxy]propoxy]-(251644-52-7)
• EPA Substance Registry System: Silane, trimethyl[3-phenyl-1-[(1R)-1-phenylethoxy]propoxy]-(251644-52-7)

Safety Data

• Hazardous Substances Data: 251644-52-7(Hazardous Substances Data)

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 52126-26-8 (R)-dihydrocinnamic acid 1-phenyl-ethyl ester 

Relevant articles and documents

Origin of diastereoselectivity in the addition of allylsilane to chiral acyclic mixed acetals

Addition of allylsilane to chiral acyclic mixed acetals has been found to proceed via an S(N)1 mechanism and a model has been proposed to explain the observed diastereoselectivity.

Acetate aldol reactions of chiral oxocarbenium ions

Chiral oxocarbenium ions have been exploited to carry out highly diastereoselective and enantioselective acetate aldol addition reactions. The chiral auxiliary has been optimized to give the product with good diastereoselectivity.