25185-94-8Relevant academic research and scientific papers
Nucleophilic fluorination facilitated by a CsF-CaF2 packed bed reactor in continuous flow
Johansen,Lindhardt
supporting information, p. 825 - 828 (2018/02/06)
A simple to prepare, dry and handle packed bed reactor carrying CsF on CaF2, towards nucleophilic fluorinations in continuous flow, is reported. The reactor also proved adaptable for silyl-ether deprotection and trifluoromethylations with Ruppert's reagent. The study includes reactor stability and scale-up investigations.
Conformational Preference of the Fluoromethyl Group in Some Benzyl Fluorides: a 13C N.M.R. Study
Adcock, William,Abeywickrema, Anil N.
, p. 181 - 187 (2007/10/02)
A number of model benzyl fluoride systems have been synthesized, end their proton-decoupled natural-abundance 13C n.m.r. spectra recorded and assigned.An analysis of the long-range five-bond coupling constants (5JCF) indicates that these parame
