251984-08-4Relevant articles and documents
[Am(C5Me4H)3]: An Organometallic Americium Complex
Goodwin, Conrad A. P.,Su, Jing,Albrecht-Schmitt, Thomas E.,Blake, Anastasia V.,Batista, Enrique R.,Daly, Scott R.,Dehnen, Stefanie,Evans, William J.,Gaunt, Andrew J.,Kozimor, Stosh A.,Lichtenberger, Niels,Scott, Brian L.,Yang, Ping
supporting information, p. 11695 - 11699 (2019/08/01)
We report the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1H NMR solution spectroscopy /solid-state UV/Vis-nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am3+ organometallic complex, [Am(C5Me4H)3] (1). This constitutes the first quantitative data on Am?C bonding in a molecular species.
Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions
Windorff, Cory J.,Dumas, Megan T.,Ziller, Joseph W.,Gaunt, Andrew J.,Kozimor, Stosh A.,Evans, William J.
, p. 11981 - 11989 (2017/10/10)
Small-scale reactions of the Pu analogues La, Ce, and Nd have been explored in order to optimize reaction conditions for milligram scale reactions of radioactive plutonium starting from the metal. Oxidation of these lanthanide metals with iodine in ether
Synthesis, structure, and 15N NMR studies of paramagnetic lanthanide complexes obtained by reduction of dinitrogen
Evans, William J.,Rego, Daniel B.,Ziller, Joseph W.
, p. 10790 - 10798 (2008/10/09)
The recently discovered LnZ3/M and LnZ2Z′/M methods of reduction (Ln = lanthanide; M = alkali metal; Z, Z′ = monoanionic ligands that allow these combinantions to generate "LnZ 2" reactivity) have been applied to provide t