252044-85-2

Upstream product

• 67883-63-0 (E)-3,7-dimethyl-1-tributylstannylocta-2,6-diene 
• 252044-84-1 3-bromo-1-chloro-4-iodo-2,5-dimethoxybenzene 
• 6358-64-1 4-chloro-2,5-dimethoxy-aniline 
• 252044-81-8 2-bromo-4-chloro-3,6-dimethoxyaniline 
• 6940-53-0 4-chloro-2,5-dimethoxy nitrobenzene 
• 6313-37-7 2,5-dimethoxy-4-nitroaniline 

Downstream Products

• 252044-88-5 5-Chloro-2-((E)-3,7-dimethyl-octa-2,6-dienyl)-3-(3-methyl-but-2-enyl)-[1,4]benzoquinone 
• 252044-86-3 1-Chloro-4-((E)-3,7-dimethyl-octa-2,6-dienyl)-2,5-dimethoxy-3-(3-methyl-but-2-enyl)-benzene 

Relevant academic research and scientific papers

A concise total synthesis of (±)-A80915G, a member of the napyradiomycin family of antibiotics

(±)-A80915G, a member of the napyradiomycin family of antibiotics, has been synthesized from 1-amino-2,5-dimethoxy-4-nitrobenzene via the sequential palladium-catalyzed cross-coupling reactions (the Stille reaction) of aryl halides with allyltins and the Diels-Alder reaction of the chloroquinone with the Danishefsky-Brassard diene.