252053-94-4Relevant articles and documents
Facile synthesis of substituted phenanthroline ligands by samarium-promoted coupling of phenanthroline with ketones.
O'Neill,Helquist
, p. 1659 - 1662 (1999)
[formula: see text] 1,10-Phenanthroline undergoes coupling with ketones promoted by samarium diiodide to produce 2-(1-hydroxyalkyl)-1,10-phenanthrolines. O-Methylation of these derivatives provides the corresponding 2-(1-methoxyalkyl)phenanthrolines. Deme
Process for 1,10-phenanthroline ligands
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Page column 13, (2010/02/06)
Process for preparing 1,10-phenanthroline ligands represented by the formula which comprises coupling a 1,10-phenanthroline of the formula with a ketone e.g. a dialkyl, cycloalkyl or bicycloalkyl ketone with a metal coupling reagent, preferably a lanthani