252057-99-1

Basic information

• Product Name: (CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₂H₂N(C₂H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[(CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₈H₁₇N)]ClO₄
• CAS NO: 252057-99-1
• Molecular Weight: 1101.68
• Mol File: 252057-99-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₂H₂N(C₂H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[(CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₈H₁₇N)]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₂H₂N(C₂H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[(CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₈H₁₇N)]ClO₄(252057-99-1)
• EPA Substance Registry System: (CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₂H₂N(C₂H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[(CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(C₈H₁₇N)]ClO₄(252057-99-1)

Safety Data

• Hazardous Substances Data: 252057-99-1(Hazardous Substances Data)

Upstream product

• 252057-97-9 (CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(CH₃CN)⁽¹⁺⁾*ClO₄^(1-)=[(CH₃)((C₆H₅)3P)2(CO)Ir(CCC₆H₄CH₃)(CH₃CN)]ClO₄ 
• 121-44-8 triethylamine 
• 74-86-2 acetylene 

Downstream Products

• 252058-02-9 ((C₆H₅)3P)2(CO)(Cl)Ir(C₂H₂N(C₂H₅)3)(C(CH₃)C(H)C₆H₄CH₃)⁽¹⁺⁾*ClO₄^(1-)=[((C₆H₅)3P)2(CO)(Cl)Ir(C₈H₁₇N)(C₁₀H₁₁)]ClO₄ 
• 252058-04-1 ((C₆H₅)3P)2(CO)(Cl)2Ir(C₂H₂N(C₂H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[((C₆H₅)3P)2(CO)(Cl)2Ir(C₈H₁₇N)]ClO₄ 

Relevant articles and documents

Reaction of an (alkyl)(alkenyl)(alkynyl)iridium(III) complex with HCl: Intramolecular C-C bond formation from alkyl, alkenyl, and alkynyl groups coordinated to "Ir(CO)(PPh3)2". H/D exchange between CH3 and DCl

Reaction of the (alkyl)(alkenyl)(alkynyl)iridium(III) complex [Ir(CH3)(CH=CHNEt3)(C≡ C(p-C6H4CH3))(CO)(PPh3) 2]ClO4 (3) with aqueous HCl initiates an intramolecular co