25226-75-9Relevant academic research and scientific papers
Liquid-phase synthesis of cyclic diene diepoxides using metal halides and hydrogen peroxide
Alimardanov, Kh. M.,Sadygov,Garibov,Abdullaeva, M. Ya.
, p. 1302 - 1308 (2013/02/21)
Optimal conditions were found for induced hydroxyhalogenation of cyclic dienes (tetrahydroindene, 4-vinylcyclohexene and 5-vinyl- and 5-cyclohexenylbicyclo[2.2.1]hept-2-enes) in the system [MHlg-HA or HHlg]-H 2O2 (or NaClO). Dehydrohalogenation of the chloro- and bromohydrins thus obtained with powdered potassium carbonate gave the corresponding diepoxy derivatives, and their hydrolysis led to mixtures of stereoisomeric tetrahydric alcohols. Pleiades Publishing, Ltd., 2012.
