252289-36-4

Upstream product

• 252289-29-5 (1S,1'S,2S,3S)-3-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-6-methylenecyclohexane-1,2-diyl bis(methanesulfonate) 
• 252289-21-7 (1'S,3R,6S)-{{6-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-3-methylcyclohex-1-en-1-yl}oxy}trimethylsilane 
• 252289-27-3 (1S,1'S,2S,3S)-3-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-6-methylenecyclohexane-1,2-diol 
• 252289-23-9 (3R,6S)-2-Bromo-6-{(S)-2-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-1-methyl-ethyl}-3-methyl-cyclohexanone 
• 252289-19-3 (1S,1'S,2S,5R)-2-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-5-methylcyclohexanol 
• 252289-24-0 (1'S,6S)-6-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-3-methylcyclohex-2-en-1-one 
• 252289-20-6 (1'S,2S,5R)-2-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-5-methylcyclohexanone 
• 252289-30-8 (1'R,2S)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane 
• 252289-34-2 (1'R,2S)-2-(4'-methylenecyclohex-2'-en-1'-yl)propan-1-ol 
• 13834-16-7 (1R,2S,5R)-2-[(S)-2-hydroxy-1-methylethyl]-5-methylcyclohexan-1-ol 
• 151-50-8 potassium cyanide 
• 250689-37-3 (1'R,2S)-2-(4'-methylenecyclohex-2'-en-1'-yl)propyl 4-nitrobenzenesulfonate 

Downstream Products

• 252289-37-5 (1'S,3R)-3-(4'-methylenecyclohex-2'-en-1'-yl)butanal 

Relevant academic research and scientific papers

Stereospecific synthesis of (-)-β-turmerone and (-)-bisacurol

The structure of (+)-β-turmerone ((+)-1a), a constituent of the rhizomes of Curcuma longa LINN., and Curcuma xanthorriza, is established as (1'R,6S)-2-methyl-6-(4'-methylenecyclohex-2'-en-1'-yl)hept-2-en-4-one by synthesis of its enantiomer (-)-1a, and of