25229-47-4Relevant articles and documents
Lewis acid-promoted rearrangement of 2,3-epoxy alcohol derivatives: Stereochemical control and selective formation of two types of chiral quaternary carbon centers from the single carbon skeleton
Kita, Yasuyuki,Matsuda, Satoshi,Inoguchi, Ryoko,Ganesh, Jnaneshwara K.,Fujioka, Hiromichi
, p. 5191 - 5197 (2007/10/03)
The Lewis acid-promoted rearrangement of 2,2,3,3-tetrasubstituted 2,3-epoxy alcohols with several kinds of protecting groups was investigated. When SnCl4 is used as a Lewis acid, the reaction proceeds in a regio- and stereo-controlled manner to