252316-80-6

Basic information

• Product Name: (2S,3S)-diacetoxy-(1R,4R)-dihydroxycyclohex-5-ene
• Synonyms: (2S,3S)-diacetoxy-(1R,4R)-dihydroxycyclohex-5-ene
• CAS NO: 252316-80-6
• Molecular Weight: 230.218
• Mol File: 252316-80-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S)-diacetoxy-(1R,4R)-dihydroxycyclohex-5-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-diacetoxy-(1R,4R)-dihydroxycyclohex-5-ene(252316-80-6)
• EPA Substance Registry System: (2S,3S)-diacetoxy-(1R,4R)-dihydroxycyclohex-5-ene(252316-80-6)

Safety Data

• Hazardous Substances Data: 252316-80-6(Hazardous Substances Data)

Upstream product

• 4381-96-8 (+/-)-(1,3/2,4)-1,2,3,4-tetra-O-acetyl-5-cyclohexene-1,2,3,4-tetrol 

Downstream Products

• 80338-90-5 (1R,2S,3S,4R)-1,2,3,4,tetrahydroxy-5-cyclohexene 

Relevant articles and documents

Enzymatic resolution of (±)-conduritol-B, a key intermediate for the synthesis of glycosidase inhibitors

Lipases from porcine pancreas, Candida cylindracea and Mucor miehei (adsorbed on support, Lipozyme IM) catalysed in t-butylmethylether the alcoholysis of rac-conduritol-B peracetate, (±)-1, by n-butanol to give enantiopure (2S,3S)-diacetoxy-(1R,4R)-dihydroxycyclohex-5-ene, (-)-3, and (1S,2R,3R,4S)-tetraacetoxy-cyclohex-5-ene, (+)-1. The enantioforms (+)- and (-)-conduritol-B, obtained after chemical hydrolysis of (-)-3 and (+)-1, respectively, may be employed to prepare both the enantiomers of conduritol-B epoxide and cyclophellitol, powerful inhibitors of glycosidases.