25245-41-4Relevant academic research and scientific papers
Synthesis of 1,2,4-trimethoxybenzene and its selective functionalization at C-3 by directed metalation
Alves, Ana P. L.,Junior, Jose Augusto B. C.,Slana, Glaucia B. A.,Cardoso, Jari N.,Wang, Qiang,Lopes, Rosangela S. C.,Lopes, Claudio C.
, p. 3693 - 3709 (2009)
A new and efficient strategy was developed for the preparation of 1,2,4-trimethoxybenzene (3, a powerful attractant of Euglossini bees) and its C-3 derivatives (7a-j), from vanillin (2) in 56% overall yield.
Pd(II)-catalyzed bromo- and chlorodecarboxylation of electron-rich arenecarboxylic acids
Peng, Xuefeng,Shao, Xiang-Feng,Liu, Zhong-Quan
supporting information, p. 3079 - 3081 (2013/07/11)
A bromo- and chlorodecarboxylation of various aromatic carboxylic acids catalyzed by Pd(II) has been developed in this work. A series of electron-rich arenecarboxylic acids gave the corresponding decarboxylative monohalogenation products under the typical reaction conditions.
