2525-37-3

Basic information

• Product Name: Cyclopropane, 1-ethenyl-2-methyl-, trans-
• CAS NO: 2525-37-3
• Molecular Formula: C6H10
• Molecular Weight: 82.1454
• Mol File: 2525-37-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropane, 1-ethenyl-2-methyl-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropane, 1-ethenyl-2-methyl-, trans-(2525-37-3)
• EPA Substance Registry System: Cyclopropane, 1-ethenyl-2-methyl-, trans-(2525-37-3)

Safety Data

• Hazardous Substances Data: 2525-37-3(Hazardous Substances Data)

Upstream product

• 23038-08-6 exo-6-Methylbicyclo<3.1.0>hexan-3-one 
• 73104-83-3 endo-6-Methylbicyclo<3.1.0>hexan-3-one 

Relevant articles and documents

Mechanistic Aspects of Gas-Phase Photodecarbonylation Reactions of Bicyclohexanones

The gas-phase photodecarbonylation and photofragmentation reactions of substituted bicyclohexan-3-ones have been studied in detail.Photolysis of these ketones yields 1,3-dienes, vinylcyclopropanes, and 1,4-dienes as detectable products.The possible mechanisms for these reactions are discussed in light of the regiochemical and stereochemical results obtained.In addition, methyl substitution at C-6 and C-2 of these ketones has been shown to have a pronounced effect on both product ratios and overall reaction efficiency.These effects are discussed in terms of stereoelectronic and electronic controls of rates of cyclopropane ring opening of intermediate acylcyclopropylcarbinyl diradicals.