2525-80-6Relevant academic research and scientific papers
Reaction of perfluorocarbonyl chlorides with ethyl- and phenylmagnesium bromides
Chapurkin,Litinskii,Leont'eva,Chapurkin
, p. 1136 - 1138 (2005)
The structure of the products formed by the reactions of perfluoroadipoyl and perfluorocyclo-hexanedicarbonyl difluorides with ethyl- and phenylmagnesium bromides depends on the nature of the radical in the organomagnesium compound. 2005 Pleiades Publishing, Inc.
Fluoro-substituted ketones from nitriles using acidic and basic reaction conditions
Raja, Erum K.,Klumpp, Douglas A.
supporting information; experimental part, p. 5170 - 5172 (2011/10/13)
Fluoro-substituted aliphatic nitriles are shown to undergo the Houben-Hoesch reactions with arenes in CF3SO3H to give fluoro-substituted ketones in good yields. The fluorine substituents appear to enhance the reactivities of the nitriles (and the nitrilium ion intermediates) compared to similar aliphatic nitriles. Fluoro-substituted ketones are also shown to be accessible through the reactions of organometallic reagents and fluoro-substituted nitriles.
REDUCTION OF POLYFLUORINATED CARBONYL COMPOUNDS BY ETHOXYMAGNESIUM BROMIDE
Dormidontov, Yu. P.,Shadrina, L. P.
, p. 241 - 244 (2007/10/02)
The reduction of perfluoroalkyl phenyl ketones and diketones with ethoxymagnesium bromide takes place readily in the absence of branching at the α-carbon atom of the aliphatic radical and in the absence of a substituent or in the presence of only one orth
