2527-77-7Relevant academic research and scientific papers
Formation of thiophenethiols by flash vacuum pyrolysis of 1,6,6aλ4-trithiapentalenes
Flammang, Robert,Barbieux-Flammang, Monique,Gerbaux, Pascal,Pedersen, Carl Th.
, p. 1261 - 1264 (2007/10/03)
The thermal behaviour of 1,6,6aλ4-trithiapentalene 3 and some methyl-substituted derivatives 5-7 has been investigated using a combination of flash vacuum pyrolysis (FVP), tandem mass spectrometry (MS-MS) and matrix isolation IR spectroscopy. the main products of the fragmentation (losses of CS and/or CH2=C=S) are shown to be thiophene-3-thiones (or the thiol tautomers) which are also shown to be readily available by direct sulfuration of thiophenes in chemical ionization (CS2 reagent gas) conditions.
