252726-89-9Relevant academic research and scientific papers
Transformations of lignans, Part IV. Acid-catalysed rearrangements of gmelinol with BF3-etherate and study of a product with a unique lignan skeleton formed by further oxidation with DDQ
Ward, Robert S.,Pelter, Andrew,Venkateswarlu, Revuru,Kamakshi, Chakicherla,Subhash, Pithani V.,Moinuddin, Syed G. A.,Hursthouse, Michael B.,Coles, Simon J.,Hibbs, David E.
, p. 13071 - 13086 (2007/10/03)
Reaction of gmelinol 1 with BF3-etherate followed by treatment with various additives gave two isomeric products 2 and 5 formed by rearrangement of the 2,6-diaryl-3,7-dioxabicyclo[3.3.0]octane skeleton. Compounds 2 and 5 on oxidation with DDQ i
Rearrangements of the 2,6-diaryl-3,7-dioxabicyclo[3.3.0] octane skeleton, Part III. Reaction of gmelinol with BF3-etherate and N,N-dimethylaniline
Ward, Robert S.,Pelter, Andrew,Venkateswarlu, Revuru,Kamakshi, Chakicherla,Lakshmi, Ayalasomayajula
, p. 14349 - 14360 (2007/10/03)
Reaction of gmelinol 1 with BF3-etherate and N,N-dimethylaniline gave a product 9 formed by rearrangement of the 2,6-diaryl-3,7-dioxabicyclo[3.3.0]octane skeleton. Compound 9 on reduction with BF3-etherate and triethylsilane produced 15 which is epimeric with di-O-methyl cycloolivil 18.
