25284-31-5

Upstream product

• 16029-98-4 trimethylsilyl iodide 
• 1675-57-6 diethynyldiphenylsilane 
• 775-12-2 diphenylsilane 
• 1066-54-2 trimethylsilylacetylene 
• 80-10-4 diphenylsilyl dichloride 

Downstream Products

• 435345-85-0 C₁₂H₁₀SiC₅H₉SiC₂H 
• 871502-36-2 [(η5-C5Me5)2Ti(η2-SiMe3C2Si(C6H5)2C2Si(CH3)3)] 
• 871502-35-1 [(η5-C5HMe4)2Ti(η2-SiMe3C2Si(C6H5)2C2Si(CH3)3)] 
• 1209004-24-9 1,1-diphenyl-2,5-bis(trimethylsilyl)-4-pentafluorophenyl-3-bis(pentafluoropheyl)borylsilane 
• 1228942-33-3 3-[bis(pentafluorophenyl)boryl]-2,5-bis(trimethylsilyl)-1,1-diphenylsilole 
• 1292785-45-5 Si(C₆H₅)2(C₂HSi(CH₃)3)(CSi(CH₃)3)CB(C₆F₅)2 
• 1228942-31-1 1,1-dimethyl-2,5-bis(trimethylsilyl)-3-bis(pentafluoropheyl)borylsilane 
• 1292785-44-4 Si(CH₃)2(C₂HSi(CH₃)3)(CSi(CH₃)3)CB(C₆F₅)2 
• 1675-57-6 diethynyldiphenylsilane 

Relevant academic research and scientific papers

Sodium triethylborohydride as a catalyst for the dehydrogenative silylation of terminal alkynes with hydrosilanes

The first example of sodium triethylborohydride-catalyzed C(sp)-H bond silylation is reported. The reaction of aromatic and aliphatic alkynes with aromatic hydrosilanes and hydrosiloxanes proceeded in a highly selective manner to afford dehydrocoupling pr

Iridium-promoted conversion of chlorosilanes to alkynyl derivatives in a one-pot reaction sequence

By making use of the catalytic potential of the iridium system [{Ir(μ-Cl)(CO)2}2]/NEt(i-Pr)2 in the synthesis of silyl-functionalized alkynes via silylative coupling of terminal alkynes/diynes with iodosilanes, we propose

Fourfold Diels-Alder Reaction of Tetraethynylsilane

A series of ethynylated silanes, including tetraethynylsilane was treated with tetraphenylcyclopentadienone at 300 8C under microwave irradiation to give the aromatized Diels-Alder adducts as sterically encumbered mini-dendrimers with up to 20 benzene rings. The sterically most congested adducts display red-shifted emission through intramolecular p-p interactions in the excited state.

NEW (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES AND A NEW CATALYTIC METHOD FOR OBTAINING NEW AND CONVENTIONAL SUBSTITUTED (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES

The present invention relates to new (triorganosilyl)alkynes and their derivatives having general formula 1 R1—C≡C—Z (I) In its second aspect, this invention relates to a new selective method for the preparation of new and conventional (triorga

NEW (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES AND A NEW CATALYTIC METHOD FOR OBTAINING NEW AND CONVENTIONAL SUBSTITUTED (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES

The present invention relates to new (triorganosilyl)alkynes and their derivatives having general formula 1 R1-C≡C-Z (I) In its second aspect, this invention relates to a new selective method for the preparation of new and conventional (triorga

Silylative coupling of terminal alkynes with iodosilanes: New catalytic activation of sp-hybridized carbon-hydrogen bonds

The [{Ir(μ-Cl)(CO)2}2] (I)-catalyzed reaction of terminal alkynes and diynes with Me3SiI with the aid of NEt(i-Pr)2 occurs smoothly, leading to the formation of mono- and bis-silyl-functionalized alkynyl derivat

Synthesis and characterisation of new oligoacetylenic silanes

Synthetic routes to a series of novel oligoacetylenic silanes with or without (hetero)aromatic bridges have been developed. The compound Me3SiC≡CSi(Ph)2C≡CSiMe3 was first prepared, which was selectively desilylated with CaCO3 in methanol at room temperature to afford the mono-protected bis(alkynyl) silane Me3SiC≡CSi(Ph)2C≡CH in moderate yield. Treatment of this mono-protected species with nBuLi, followed by silylation with Ph2SiCl2, gives a good yield of Me3SiC≡CSi(Ph)2C≡CSi(Ph)2 C≡CSi(Ph)2C≡CSiMe3, with alternating silicon and acetylene units. A range of linear silicon-linked oligoalkynes containing phenylene, bithienylene and anthrylene rings, HC≡CRC≡CSi(Ph)2C≡CRC≡CH and HC≡CRC≡CSi(Ph)2C≡CRC≡CSi(Ph)2 C≡CRC≡CH (R = 1,4-phenylene, 5,5′-bithienylene or 9,10-anthrylene), were synthesised by condensation reactions of Ph2SiCl2 with the components obtained in situ from a HC≡CRC≡CH-nBuLi mixture in THF and the products were isolated by chromatography on silica. All these new compounds have been characterised by IR, 1H and 13C NMR and UV/VIS spectroscopies and mass spectrometry. The single-crystal X-ray structure of HC≡C(p-C6H4)C≡CSi(Ph)2C≡C (p-C6H4)C≡CSi(Ph)2C≡C(p-C 6H4C≡CH has been determined, showing that two silicon atoms and six acetylene units constitute the backbone of the molecule.