252898-06-9Relevant academic research and scientific papers
Benzyl-tris(trimethylsilyl)methyl tin dihalides, {(CH3)3Si}3C(C6H5-CH 2)SnHal2 with Hal = Cl, Br, I
Schwarz,Lissner,Weidlein
, p. 1807 - 1812 (2008/10/08)
The tin tetrahalides SnHal4 (Hal = Cl, Br, I) react with base-free tris(trimethylsilyl)methyllithium (Tsi-Li) solved in toluene to form the trihalides Tsi-SnHal3. But when the reaction is carried out in a 1:2 molar ratio at 60 °C in toluene, Tsi-H, Tsi-Hal and benzyl-trisyl lin-dihalides are formed in good yields, respectively. The nmr (1H, 13C, 29Si, 119Sn) and the Raman spectra are discussed, the X-ray structure analyses of the dibromide as well as the diiodide have been measured.
