252935-80-1Relevant academic research and scientific papers
Asymmetric palladium-catalyzed intramolecular α-arylation of aldehydes
Garcia-Fortanet, Jorge,Buchwald, Stephen L.
supporting information; experimental part, p. 8108 - 8111 (2009/04/13)
(Chemical Equation Presented) Phoxy ligand: The first catalytic method for the asymmetric palladium-catalyzed intramolecular α-arylation of α-branched aldehydes was developed (see scheme). This process is distinguished by the high yields and enantioselectivities that can be obtained, making this protocol a useful synthetic tool for further applications.
Efficient synthesis of 2- and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr(II)/Ni(II)-mediated carbonyl addition sequence
Halterman, Ronald L.,Zhu, Chengian
, p. 7445 - 7448 (2007/10/03)
An efficient new synthesis of 2- and 3-substituted indenes has been developed based on the nickel-catalyzed chromium(II)-promoted addition of aryl bromides to a tethered ketone carbonyl. Several tethered bromoaryl ketones were prepared through enolate alk
