253129-45-2Relevant academic research and scientific papers
Intramolecular addition of stabilized enolates to (η6-arene)ruthenium complexes: Synthesis of Ru-coordinated azaspirocycles
Pigge, F. Christopher,Fang, Shiyue,Rath, Nigam P.
, p. 1851 - 1854 (2008/02/11)
(formula presented) Stabilized enolates attached to cationic (arene)RuIICp complexes via an amide linkage were found to participate in nucleophilic aromatic addition reactions resulting in the formation of novel cyclohexadienyl-Ru azaspirocycles. Enolate addition to the activated arene ring was found to proceed with complete stereoselectivity.
