2532-15-2

Basic information

• Product Name: sodium 4-bromobenzoate
• Synonyms: sodium 4-bromobenzoate;4-Bromobenzoic acid sodium salt;Benzoic acid, 4-broMo-, sodiuM salt
• CAS NO: 2532-15-2
• Molecular Formula: C₇H₄BrO₂*Na
• Molecular Weight: 0
• Mol File: 2532-15-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 299.8°Cat760mmHg
• Flash Point: 135.1°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.000519mmHg at 25°C
• CAS DataBase Reference: sodium 4-bromobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: sodium 4-bromobenzoate(2532-15-2)
• EPA Substance Registry System: sodium 4-bromobenzoate(2532-15-2)

Safety Data

• Hazardous Substances Data: 2532-15-2(Hazardous Substances Data)

Usage

General Description

Sodium 4-bromobenzoate is a chemical compound with the molecular formula C7H4BrNaO2. It consists of a sodium cation and a 4-bromobenzoate anion, which is derived from benzoic acid and contains a bromine atom attached to the benzene ring at the 4-position. sodium 4-bromobenzoate is commonly used as a reagent in organic synthesis, particularly in the preparation of aromatic carboxylic acids and their derivatives. It is also utilized in the pharmaceutical industry for the synthesis of active pharmaceutical ingredients. Sodium 4-bromobenzoate is a white crystalline solid that is soluble in polar solvents such as water and alcohols, and it is often used as a precursor for the preparation of other organic compounds.

InChI:InChI=1/C7H5BrO2.Na/c8-6-3-1-5(2-4-6)7(9)10;/h1-4H,(H,9,10);/q;+1/p-1

Upstream product

• 18292-63-2 1-(p-bromobenzoyl)aziridine 
• 1122-91-4 4-bromo-benzaldehyde 
• 586-76-5 4-Bromobenzoic acid 
• 824-78-2 4-nitrophenol sodium salt 

Downstream Products

• 58003-22-8 3-Phenyl-3-(p-brom-benzoyloxy)-methacrylsaeure-diethylamid 
• 6420-77-5 allyl p-bromobenzoate 
• 100477-66-5 silver(I) p-bromobenzoate 
• 586-76-5 4-Bromobenzoic acid 
• 824-78-2 4-nitrophenol sodium salt 
• 1454690-00-6 sodium 4-((E)-[2-D]vinyl)benzoate 
• 77124-40-4 4-vinyl-benzoic acid sodium salt 
• 900937-58-8 2-oxopropyl 4-bromobenzoate 
• 1431463-30-7 2-hydroxy-2-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]propyl 4-bromobenzoate 
• 1431463-29-4 2-[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]-2-hydroxypropyl 4-bromobenzoate 
• 1431463-28-3 2-[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]-2-hydroxypropyl 4-bromobenzoate 
• 1186200-21-4 3-methyl-2-(pyridin-2-yl)phenyl 4-bromobenzoate 

Relevant articles and documents

The effect of 4-halogenobenzoate ligands on luminescent and structural properties of lanthanide complexes: Experimental and theoretical approaches

The ligands 4-fluorobenzoate (4-fba), 4-chlorobenzoate (4-cba), 4-bromobenzoate (4-bba) and 4-iodobenzoate (4-iba) were chosen in order to synthesize europium(iii), gadolinium(iii) and terbium(iii) complexes and compare the effect of halogens on their phy

Effect of Distortion on the Hydrolytic Reactivity of Amides. 2. N-Pyramidalization: Decomposition of N-Benzoylaziridines in Aqueous Media

The decomposition of para-substituted N-benzoylaziridines (H, OCH3, NO2, Br) in buffered aqueous media is studied at 25 deg C as a function of pH in order to assess the effect of N-pyramidalization on the hydrolytic reactivity of the amide bond.Overall, the reaction shows three dominant terms: OH- and H2O attack on the neutral form and H2O attack on the protonated form of the amide.In base, the exclusive reaction is rate-limiting and irreversible attack of OH- on the C=O unit leading to normal hydrolytic products.This is shown by the first-order dependence on -> from pH 8 to 14 of the hydrolysis rate and by the fact that ca. 50percent 18O-enriched amide recovered from the hydrolysis medium as a function of time shows no 18O loss.Relative to N,N-dimethylbenzamide (kOH-25 deg C = 6.0 * 10-6 M-1 s-1), N-benzoylaziridine is ca. 200 000-fold more susceptible to OH- attack (kOH-25 deg C = 1.1 M-1 s-1).The kOH- terms follow a ?ρ relationship with ρ = 1.68.In acid, the products are not the expected hydrolytic ones of benzoic acid and aziridine.Rather, exclusive ring opening occurs to give p-X-C6H4C(=O)NHCH2CH2OX.In acetate buffers, product analysis by 1H NMR indicates that the ring-opened material consists of alcohol and acetate (X = H and C(=O)CH3).