25355-09-3Relevant academic research and scientific papers
Products and mechanism of the reaction of ozone with acetals
Brudnik, B. M.,Kuramshin, E. M.,Imashev, U. B.,Zlotskii, S. S.,Rakhmankulov, D. L.
, p. 608 - 614 (2007/10/02)
As a result of the ozonized oxidation of acetals at -20-60 deg C esters and alcohols (or glykol monoesters), hydroperoxides, and water accumulate in parallel in the initial period of the reaction.The formation of esters and alcohols is explained by molecular paths, and the formation of hydroperoxides and water is explained by radical paths; the yields of hydroperoxides and water can be reduced by reducing the ozonization temperature.The reactivity of acetals increases with increase in the size of the alkoxyl group.
