25363-21-7Relevant academic research and scientific papers
Lewis Acid Complexed Heteroatom Carbanions; A New Concept for α-Metallation of Tertiary Amines
Kessar, Satinder V.,Singh, Paramjit,Vohra, Rahul,Kaur, Nachhattar Pal,Singh, Kamal Nain
, p. 568 - 570 (2007/10/02)
BF3 complexes of typical benzylic, allylic and saturated N-methyl tertiary amines were α-lithiated, with lithium tetramethylpiperidide (LTMP) or sec-butyllithium, and were treated with electrophiles.
Syntheses des alkyl-1 cyclanols fonctionnalises aux positions α, β et γ de la chaine hydrocarbonee
Canonne, P.,Belley, M.,Fytas, G.,Plamondon, J.
, p. 168 - 173 (2007/10/02)
We have developed a general and versatile synthesis of N,N-dialkylaminoalkyl-, 1-chloroalkyl-, 1-phenoxyalkyl-, 1-thiophenoxyalkyl-, 1-diethoxyalkyl-, and 1-(1,3-dithiolane)alkylcyclanols in good yields by the reaction of α,ω-bis(bromomagnesio)alkanes with the corresponding functionalized carboxylic acid esters.
α-METALLIERTE AMINE DURCH DEPROTONIERUNG ALIPHATISCHER N-METHYLAMINE
Ahlbrecht, Hubertus,Dollinger, Horst
, p. 1353 - 1356 (2007/10/02)
Aliphatic N-methylamines can be deprotonated by means of s-butyllithium/potassium t-butoxide to give dialkylaminomethyl potassium or after metal exchange the more nucleophilic dialkylaminomethyl lithium.
