253668-53-0Relevant academic research and scientific papers
A Comparison of the Flash Vacuum Pyrolysis Products of Some N-Acylbenzotriazoles and N-Acylbenzisoxazolones
Baradarani, Mehdi M.,Khalafy, Jabbar,Prager, Rolf H.
, p. 775 - 780 (1999)
The flash vacuum pyrolysis (f.v.p.) products of 2-(1H-benzotriazol-1-ylcarbonyl)benzonitrile, methyl 2-(1H-benzotriazol-1-ylcarbonyl)benzoate and 1-(2-chloromethylbenzoyl)-1H-benzotriazole and the corresponding benzisoxazolones have been characterized. The benzotriazole derivatives gave compounds whose origin suggests the predominance of radical processes. At lower temperatures the benzisoxazolones gave benzoxazole products consistent with a singlet carbene intermediate, but which had triplet diradical properties at higher temperatures, leading to the formation of acridine from the chloromethyl compound. The major low-temperature f.v.p. product from the (chloromethylbenzoyl)benzisoxazolone was indolo[1,2-b]benzoxazole.
