253680-80-7

Upstream product

• 100945-15-1 N-(benzyloxycarbonyl)phosphonoglycine trimethyl ester 
• 78009-77-5 2,3,5-tri-O-benzyl-4-O-(tert-butyldimethylsilyl)-aldehydo-D-arabinose 
• 253680-75-0 2,3,5-tri-O-benzyl-4-O-(tert-butyldimethylsilyl)-D-arabinose ethylene dithioacetal 
• 253680-73-8 2,3,5-tri-O-benzyl-D-arabinose ethylene dithioacetal 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 

Downstream Products

• 253680-81-8 methyl (Z,4R,5S,6R)-4,5,7-tribenzyloxy-2-benzyloxycarbonylamino-6-hydroxy-2-heptenoate 
• 862888-51-5 allyl (Z,4R,5S,6R)-2-benzyloxycarbonylamino-6-hydroxy-4,5,7-tribenzyloxy-2-heptenoate 
• 862888-56-0 allyl (Z,4R,5R,6R)-6-azido-2-benzyloxycarbonylamino-4,5,7-tribenzyloxy-2-heptenoate 
• 862888-46-8 (Z,4R,5S,6R)-N-2'-oxopropyl-2-benzyloxycarbonylamino-6-hydroxy-4,5,7-tribenzyloxy-2-heptenamide 
• 862888-55-9 allyl (Z,4R,5S,6R)-2-benzyloxycarbonylamino-6-tert-butyldimethylsiloxy-4,5,7-tribenzyloxy-2-heptenoate 
• 862888-59-3 (Z,4R,5S,6R)-N-2'-oxopropyl-2-benzyloxycarbonylamino-6-monochloromethanesulfonyl-4,5,7-tribenzyloxy-2-heptenamide 
• 862888-53-7 (Z,4R,5S,6R)-N-2'-oxopropyl-2-benzyloxycarbonylamino-6-tert-butyldimethylsiloxy-4,5,7-tribenzyloxy-2-heptenamide 
• 862888-57-1 (Z,4R,5S,6R)-N-2'-hydroxypropyl-2-benzyloxycarbonylamino-6-tert-butyldimethylsiloxy-4,5,7-tribenzyloxy-2-heptenamide 
• 253680-85-2 methyl (Z,4R,5R,6S)-6-azido-4,5,7-tribenzyloxy-2-benzyloxycarbonylamino-2-heptenoate 
• 253680-92-1 methyl (E,3R,4R,5S)-N-benzyloxycarbonyl-α-(3,4-dibenzyloxy-5-benzyloxymethylpyrrolidine-2-ylidene)glycinate 

Relevant academic research and scientific papers

Application of intramolecular 1,3-dipolar cyclic addition of azide and olefin; Construction of (pyrrolidine-2-ylidene)glycinate and glycinamides

Oxopropyl E-(pyrrolidine-2-ylidene)glycinamide (5c) and allyl E-(pyrrolidine-2-ylidene)glycinate (5d) were effectively synthesized from 2,3,5-tri-O-benzyl-4-O-tert-butyldimethylsilyl(TBDMS)-D-arabinal (7) using intramolecular 1,3-dipolar cyclic reaction o

An efficient synthesis of (pyrrolidin-2-ylidene)glycinate using intramolecular 1, 3-dipolar cycloaddition of azide and olefin

Methyl and tert-butyl (E-)-(pyrrolidin-2-ylidene)glycinates 3a and 3b were efficiently and stereoselectively synthesized from 2, 3, 5-tri-O- benzylarabinose using Horner-Emmons olefination of arabinal 9 and phosphorylglycine ester and intramolecular 1, 3-