25372-07-0Relevant academic research and scientific papers
Polynuclear architectures with di- and tricarbene ligands
Rit, Arnab,Pape, Tania,Hahn, F. Ekkehardt
, p. 6393 - 6401 (2011)
The 1,3,5-triimidazolium-substituted benzene cation in H 3-1(PF6)3 reacts with Hg(OAc)2 to yield the cylinder-like trinuclear hexacarbene complex [Hg3(1) 2](PF6)6. Rea
Synthesis of binuclear palladium complexes with a rigid phenylene bridge linker
Wang, Guangying,Liu, Gang,Du, Yufeng,Li, Wenshu,Yin, Shuhui,Wang, Shuzhan,Shi, Yanhui,Cao, Changsheng
, p. 691 - 698 (2014)
The complexes [PdX2Py]2(di-NHC) (X = Br or Cl) in which di-NHC represents a di-N-heterocyclic carbene, featuring a rigid phenylene spacer between the carbene units, have been prepared from reactions of the corresponding diimidazolium
(CC*) Cyclometalated binuclear N-heterocyclic biscarbene platinum(ii) complexes-highly emissive phosphorescent emitters
Tronnier, Alexander,Strassner, Thomas
, p. 9847 - 9851 (2013)
A series of bimetallic N-heterocyclic carbene (NHC) platinum(ii) complexes with the general formula [Pt(NHC)(L)]2Ph were synthesized, which are composed of two [Pt(NHC)(L)] (L = acetylacetone, dipivaloylmethane or dimesitoylmethane; NHC = 3-met
Mesomorphic and ion conducting properties of dialkyl(1,4-phenylene) diimidazolium salts
Noujeim, Nadim,Samsam, Salim,Eberlin, Ludovic,Sanon, Samantha H.,Rochefort, Dominic,Schmitzer, Andreea R.
, p. 10914 - 10920,7 (2012)
A new family of dialkyl(1,4-phenylene)diimidazolium salts has been synthesized. Salts containing triflate and bis(trifluoromethanesulfonyl)imide anions and different alkyl chains have been prepared. The molecular structures of didodecyl(1,4-phenylene)diim
Tuning Gate-Opening of a Flexible Metal–Organic Framework for Ternary Gas Sieving Separation
Dong, Qiubing,Zhang, Xin,Liu, Shuang,Lin, Rui-Biao,Guo, Yanan,Ma, Yunsheng,Yonezu, Akira,Krishna, Rajamani,Liu, Gongpin,Duan, Jingui,Matsuda, Ryotaro,Jin, Wanqin,Chen, Banglin
, p. 22756 - 22762 (2020)
In comparison with the fast development of binary mixture separations, ternary mixture separations are significantly more difficult and have rarely been realized by a single material. Herein, a new strategy of tuning the gate-opening pressure of flexible
Covalent triazine frameworks for the selective sorption of palladium from highly acidic radioactive liquid wastes
Cai, Yimin,Feng, Wen,Liu, Hui,Qin, Song,Sun, Mengqi,Wu, Pengcheng,Ye, Jiawei,Yuan, Lihua,Zeng, Yaxin
supporting information, p. 27320 - 27331 (2021/12/24)
Efficient palladium recovery from high level liquid wastes (HLLW) is of increasing priority for sustainable development and addressing issues in radioactive waste treatment. However, searching for robust materials for palladium sorption, in the presence o
Nucleation of Tiny Silver Nanoparticles by Using a Tetrafacial Organic Molecular Barrel: Potential Use in Visible-Light-Triggered Photocatalysis
Mondal, Bijnaneswar,Bhandari, Pallab,Mukherjee, Partha Sarathi
supporting information, p. 15007 - 15015 (2020/10/19)
Coordination-driven self-assembly of discrete molecular architectures of diverse shapes and sizes has been well studied in the last three decades. Use of dynamic imine bonds for designing analogous metal-free architectures has become a growing challenge r
Ionic conductors containing phenyl/biphenyl and hydroxyalkyl as well as preparation method and application of ionic conductors
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Paragraph 0013, (2018/09/08)
The invention belongs to the technical field of organic photoelectric materials, particularly relates to functional ionic conductors as well as a preparation method and application thereof, and in particular relates to functionalized ionic conductors cont
Function-oriented ionic polymers having high-density active sites for sustainable carbon dioxide conversion
Chen, Yaju,Luo, Rongchang,Bao, Junhui,Xu, Qihang,Jiang, Jun,Zhou, Xiantai,Ji, Hongbing
, p. 9172 - 9182 (2018/05/28)
On the basis of the development of function-oriented synthesis (FOS), we presented for the first time an efficient and one-pot construction of functional ionic polymers (FIPs) through the phenol-formaldehyde condensation process (pre-synthetic approach); FIPs had high density of Br?nsted acidic and ionic sites. Considering the electrophilic-nucleophilic dual activation of phenolic hydroxyl groups and bromide anions, the imidazolium-based FIP-Im exhibited high activity for metal-, solvent- and additive-free synthesis of cyclic carbonates from CO2 and epoxides under mild conditions. Then, to obtain higher ionic density and a more flexible skeleton, FIP-Im@QA was also prepared by implanting quaternary ammonium (QA) in the framework of FIP-IMvia the Williamson ether synthesis (post-synthetic modification), which demonstrated high efficiency in the N-formylation reaction of multitudinous secondary amines with CO2 and PhSiH3 at ambient temperature. More interestingly, these function-oriented catalysts were compatible with the target transformation under low CO2 concentration (15% in 85% N2, v/v) and were also reused for more than six times without a significant loss of activity and selectivity. Therefore, this study could not only facilitate the design and construction of FIPs, but also provide sustainable protocols for efficient production of value-added chemicals from CO2 under mild conditions.
Metal complexes with di(N-heterocyclic carbene) ligands bearing a rigid: Ortho -, meta or para -phenylene bridge
Monticelli, Marco,Tubaro, Cristina,Baron, Marco,Basato, Marino,Sgarbossa, Paolo,Graiff, Claudia,Accorsi, Gianluca,Pell, Thomas P.,Wilson, David J. D.,Barnard, Peter J.
, p. 9540 - 9552 (2016/07/06)
Three novel dinuclear bis-dicarbene silver(i) complexes of general formula [Ag2(MeIm-phenylene-MeIm)2](PF6)2 (Im = imidazol-2-ylidene) were synthesized. The corresponding copper(i) and gold(i) complexes were obt
