25385-68-6Relevant academic research and scientific papers
Fluoroalkyl derivatives of protected glycerol by nucleophilic substitution. Fluorine-containing amphiphilic mono- and bis-methacrylates
Kvicala, Jaroslav,Dolensky, Bohumil,Paleta, Oldrich
, p. 117 - 125 (1997)
The tosylate of protected glycerol (solketal, 4-(hydroxymethyl)-2,2-dimethyl-1,3-dioxolane) was fluoroalkylated by a nucleophilic substitution reaction with sodium polyfluoroalkoxides. On deprotection, 3-O-fluoroalkylated glycerol was obtained which was converted to mono- and bis-methacrylates; analogous methacrylate derivatives were prepared from 3,3,4,5,5,5-hexafluoro-pentane-1,2-diol.
Features of reaction between fluorine-containing glycidyl ethers and alcohols in basic medium
Bazhin,Gorbunova,Zapevalov,Kirichenko,Saloutin
, p. 656 - 659 (2008/02/08)
The reaction of fluorine-containing glycidyl ethers with various alcohols (i-PrOH, MeOH, PhOH, 2,2,3,3-tetrafluoropropanol) in basic medium resulted in products of regioselective opening of the oxirane ring. In reaction of 2,2,3,3-tetrafluoropropyloxymeth
