254099-17-7Relevant academic research and scientific papers
First Pauson-Khand reaction on sugar acetylenes
Isobe, Minoru,Takai, Shigeyuki
, p. 122 - 125 (1999)
Pauson-Khand reaction was achieved on the sugar acetylenes having an allylic ether substituent at the two-position of the tetrahydropyran ring to provide tri-cyclic products with high stereospecificity. This is the first example of Pauson-Khand reactions with compounds on carbohydrate or tetrahydropyranose ring, and the scope is described.
