25415-09-2Relevant academic research and scientific papers
Facile generation of a strained cyclic vinyl cation by thermal solvolysis of cyclopent-1-enyl-λ3-bromanes
Miyamoto, Kazunori,Shiro, Motoo,Ochiai, Masahito
supporting information; experimental part, p. 8931 - 8934 (2010/02/28)
Last of the cyclic vinyl cations: The simple solvolysis of cyclopent-1 -enyl-13-bromane efficiently generates the highly strained cyclopent-1 -enyl cation at room temperature (see scheme). The very high nucleofugality of the aryl-13-bromanyl groups are re
Studies on the nitrosation of N-silylated cyclopenftenylamines
Alvarez, Roberto Martínez,Vázquez, Angel Sánchez,Hananck, Michael,Subramanian
, p. 227 - 233 (2007/10/03)
The diazotization of N-silylated N-methyl- and N-phenylcyclopentenylamines affords products derived from intermediate methyl- and phenyldiazonium ions. However, when this method is applied to N,N-bissilylated cyclopentenylamines, the products obtained do not confirm the formation of a cyclopentenyl cation intermediate.
