25436-74-2 Usage
Uses
Tris(triethylsilyl)silane is used as a directing group for various regioand stereo-selective reactions in the field of organic chemistry. Its ability to participate in hydrogen abstraction reactions results in the formation of highly stable silyl radicals, which can be utilized in a wide range of applications.
Used in Organic Chemistry:
Tris(triethylsilyl)silane is used as a reagent for promoting selective reactions, such as cross-coupling and deprotection reactions, due to its ability to form stable silyl radicals upon hydrogen abstraction. This property allows chemists to control the regioand stereo-selectivity of the reactions, leading to the formation of desired products with high yields and purity.
Used in Material Science:
In the field of material science, tris(triethylsilyl)silane can be employed as a precursor for the synthesis of various silicon-containing materials, such as ceramics, glasses, and polymers. The unique properties of these materials, including their thermal stability, mechanical strength, and optical properties, make them suitable for a wide range of applications, from electronics to aerospace.
Used in Pharmaceutical Industry:
Tris(triethylsilyl)silane can also be used in the pharmaceutical industry as a synthetic intermediate for the preparation of various drug molecules. Its ability to form stable silyl radicals can be exploited in the development of new synthetic routes to complex organic molecules, potentially leading to the discovery of novel therapeutic agents.
Check Digit Verification of cas no
The CAS Registry Mumber 25436-74-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,5,4,3 and 6 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 25436-74:
(7*2)+(6*5)+(5*4)+(4*3)+(3*6)+(2*7)+(1*4)=112
112 % 10 = 2
So 25436-74-2 is a valid CAS Registry Number.
25436-74-2Relevant academic research and scientific papers
Super silyl stereo-directing groups for complete 1,5-Syn and -anti stereoselectivities in the aldol reactions of β-siloxy methyl ketones with aldehydes
Yamaoka, Yousuke,Yamamoto, Hisashi
supporting information; experimental part, p. 5354 - 5356 (2010/07/04)
In this communication, we report that substrate-controlled 1,5-syn and -anti stereoinduction in the aldol reaction of β-tris(trialkylsilyl)siloxy methyl ketones can be achieved with high diastereoselectivities. Tris(trialkylsilyl)silyl groups are easily p
