25462-37-7Relevant articles and documents
Enantiopure hydroxymethylated cycloalkenols as privileged small molecular multifunctional scaffolds for the asymmetric synthesis of carbocycles
Kumar, Rajan,Rej, Rohan Kalyan,Halder, Joydev,Mandal, Haridas,Nanda, Samik
, p. 498 - 512 (2016)
Enantiopure hydroxymethylated cycloalkenols bearing a quaternary stereocenter have been synthesized by a Pybox mediated enantioselective desymmetrization method. The synthesized cycloalkenols serve as starting precursors for the construction of several ch
Total synthesis of (+/-)-acetomycin and design of esterase-resistant analogs.
Uenishi,Kobayashi,Komine,Okadai,Yonemitsu,Sasaki,Yamada
, p. 517 - 523 (2007/10/03)
The synthesis of acetomycin and related analogs was investigated. Acetomycin was synthesized from diethyl allyl(methyl)malonate in 6.5% yield over 18 steps. The total number of steps was improved compared to our previous synthesis; i.e., four steps shorte