254756-02-0Relevant articles and documents
Diastereoselective [2,3]-sigmatropic rearrangements of lithium N-benzyl-O-allylhydroxylamides bearing a stereogenic centre adjacent to the migration terminus
Bull, Steven D.,Davies, Stephen G.,Domingez, Sara Hernandez,Jones, Simon,Price, Anne J.,Sellers, Thomas G.R.,Smith, Andrew D.
, p. 2141 - 2150 (2007/10/03)
The diastereoselective [2,3]-sigmatropic rearrangements of lithium N-benzyl-O-allylhydroxylamides bearing a stereogenic centre adjacent to the migration terminus are examined. (E)-N-Benzyl-O(4-phenylpent-2-enyl)hydroxylamine rearranges in 30% de to afford