2550-37-0

Upstream product

• 64847-82-1 cyclohexylmethylene diacetate 
• 100-49-2 cyclohexylmethyl alcohol 

Downstream Products

• 119785-31-8 <1α,2α(Z),3α,4α>-(+/-)-7-<3-<<(Cyclohexylmethyl)thio>methyl>-7-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoic acid 
• 79505-76-3 N-(2-furylmethyl)-4-cyclohexylmethylsulfonyl-5-sulfamoyl-orthanilic acid phenyl ester 
• 85958-47-0 Sodium N-(2-furylmethyl)-4-cyclohexylmethylsulfonyl-5-sulfamoyl-orthanilate 
• 170914-23-5 3-[1-[(Cyclohexylmethyl)thio]phenylmethyl]-4-hydroxy-6-phenyl-2H-pyran-2-one 
• 1051887-04-7 C₁₅H₂₈S₃ 
• 1051886-95-3 C₁₄H₂₆S₃ 
• 4081-54-3 Ag⁽¹⁺⁾*C₇H₁₃S^(1-) 
• 944338-15-2 2-aza-3-(cyclohexylmethylthio)-3-phenoxyprop-2-enenitrile 

Relevant academic research and scientific papers

Thioacetate deprotection

A method of thioacetate deprotection by providing a compound of the formula R1—S—CO—R2, and reacting the compound with a quaternary ammonium cyanide salt in the presence of a protic solvent in an inert atmosphere to convert the compound to a product of the formula R1—SH. R1 is an organic group in which the bonding to sulfur is through a saturated carbon, and R2 is an aliphatic group.

Correlation pKa - activitee catalitique des thiols dans la reeaction d'hydrolyse de l'aceetate de p-nitropheenyle

The kinetic study of the hydrolysis of p-nitrophenylacetate in the presence of primary thiols indicates the thiolate anion as the sole catalytic species.Comparison of the true second order constants (kRS-) reveals that purely aliphatic primary thiols behave differently from aromatic α-substituted primary thiols.In the latter group a correlation can be established between the true second order rate constants and the pKSH values by means of the Broensted equation log kRS- = βpKSH + C, with β equal to 0.40 and C equal to -0.85.