255861-19-9

Basic information

• Product Name: (7S,8S,10bS)-7-(2-Bromo-6-methoxyphenoxy)-8-[tert-butyl(dimethyl)silyloxy]-5,6,7,8,9,10-hexahydro-1H-oxazolo[4,3-a]isoquinolin-3-one
• Synonyms: (7S,8S,10bS)-7-(2-Bromo-6-methoxyphenoxy)-8-[tert-butyl(dimethyl)silyloxy]-5,6,7,8,9,10-hexahydro-1H-oxazolo[4,3-a]isoquinolin-3-one
• CAS NO: 255861-19-9
• Molecular Weight: 524.527
• Mol File: 255861-19-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (7S,8S,10bS)-7-(2-Bromo-6-methoxyphenoxy)-8-[tert-butyl(dimethyl)silyloxy]-5,6,7,8,9,10-hexahydro-1H-oxazolo[4,3-a]isoquinolin-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (7S,8S,10bS)-7-(2-Bromo-6-methoxyphenoxy)-8-[tert-butyl(dimethyl)silyloxy]-5,6,7,8,9,10-hexahydro-1H-oxazolo[4,3-a]isoquinolin-3-one(255861-19-9)
• EPA Substance Registry System: (7S,8S,10bS)-7-(2-Bromo-6-methoxyphenoxy)-8-[tert-butyl(dimethyl)silyloxy]-5,6,7,8,9,10-hexahydro-1H-oxazolo[4,3-a]isoquinolin-3-one(255861-19-9)

Safety Data

• Hazardous Substances Data: 255861-19-9(Hazardous Substances Data)

Upstream product

• 249642-32-8 C₂₅H₂₃NO₆ 
• 200638-14-8 3-<2-<(5S,6S)-5,6-Di(benzoyloxy)cyclohex-1-enyl>ethyl>-<1,3>oxazolidine-2,4-dione 
• 226255-51-2 (5S,6S)-5,6-Di(benzoyloxy)-1-(2-bromoethyl)cyclohex-1-ene 
• 200638-10-4 (7R,8S,10bS)-7,8-Dihydroxy-1,5,6,7,8,9,10,10b-octahydro-oxazolo[4,3-a]isoquinolin-3-one 
• 164021-78-7 (1S,2R)-3-(2-bromoethyl)cyclohex-5-ene-1,2-diol 
• 103-63-9 1-phenyl-2-bromoethane 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 28165-49-3 6-bromoguaiacol 
• 255861-21-3 8-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-1,5,6,7,8,9,10,10b-octahydro-oxazolo[4,3-a]isoquinolin-3-one 

Relevant articles and documents

Comparison of approaches to ent-morphine via radical, cationic, and heck-type cyclizations

3-(2-|6S-12-Bromo-6-methoxyphenoxy)-5S-[tert-buty](dimethyl)silyloxy) cyclohex-1-en-1-yl|-ethyl)oxazol-2(3H)-one 14 was subjected to Heck cyclization conditions to afford dibenzofuran derivative 16. The comparison of stepwise vs cascade approaches to 8 vi