256397-96-3

Upstream product

• 2937-50-0 Allyl chloroformate 
• 256397-94-1 (1R,4R)-1-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]-4-O-(tert-butyldimethylsilyl)pent-2-yne-1,4-diol 
• 256397-91-8 [2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]aldehyde 
• 75858-32-1 [2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]methanol 

Downstream Products

• 256398-03-5 methyl (3S,4E,6S)-6-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]-6-(2,4-dichlorobenzoyloxy)-2-methoxycarbonyl-3-methylhex-4-enoate 
• 256397-99-6 (1S,4R)-1-O-allyloxycarbonyl-1-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]-4-O-ethoxycarbonylpent-2-yne-1,4-diol 
• 256398-02-4 methyl (3S,4E,6S)-6-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]-6-hydroxy-2-methoxycarbonyl-3-methylhex-4-enoate 
• 256398-00-2 (1S,4R)-1-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]-4-O-ethoxycarbonylpent-2-yne-1,4-diol 
• 256398-01-3 (1S,4R)-1-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]-4-O-ethoxycarbonylpent-2-ene-1,4-diol 
• 256397-98-5 (1S,4R)-1-O-allyloxycarbonyl-1-[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]pent-2-yne-1,4-diol 

Relevant academic research and scientific papers

A new synthetic approach toward (+)-ambruticin analogs: Preparation of a C10-C11 cis-isomer fragment

A new methodology has been applied to synthesize an isomer of the west part of (+)-ambruticin based on an efficient asymmetric de novo access to the A unit and sequential stereospecific reactions catalyzed by Pd0 for the construction of the B unit.