25676-67-9Relevant academic research and scientific papers
The structural and electrochemical consequences of hydrogenating copper N2S2 Schiff base macrocycles
Trotter, Katherine D.,Taylor, Michelle K.,Forgie, John C.,Reglinski, John,Berlouis, Leonard E.A.,Kennedy, Alan R.,Spickett, Corinne M.,Sowden, Rebecca J.
scheme or table, p. 1529 - 1538 (2010/08/05)
A series of cis and trans tetradentate copper macrocyclic complexes, of ring size 14-16, that employ amine and thioether donor groups are reported. Apart from 5,6,15,16-bisbenzo-8,13-diaza-1,4-dithia-cyclohexadecane copper(I) (cis-[Cu(H4Nb
Halogen-lithium exchange versus deprotonation: regioselective mono- and dilithiation of aryl benzyl sulfides. A simple approach to α,2-dilithiotoluene equivalents
Kli?, Tomasz,Serwatowski, Janusz,Wesela-Bauman, Grzegorz,Zadrozna, Magdalena
experimental part, p. 1685 - 1689 (2010/06/13)
Halogen-lithium exchange and deprotonation reactions between aryl benzyl sulfides and alkyllithiums were investigated. The resultant mono- and dilithiated intermediates were converted into the corresponding aldehydes and boronic, or carboxylic acids in good yields. It was found that diethyl ether stabilizes the ortho-lithiated compounds toward isomerisation to the benzylic derivatives. The process occurs easily in THF at low temperature and is a facile route to the α,2-dilithiotoluene derivative which can be transformed into a dicarboxylic acid on treatment with CO2.
Macrocyclic [Cu(I/II)(bite)](+/2+) (bite = biphenyldiimino dithioether): An example of fully-gated electron transfer and its biological relevance
Flanagan, Scott,Dong, Jun,Haller, Kenneth,Wang, Shengke,Scheidt, W. Robert,Scott, Robert A.,Webb, Thomas R.,Stanbury, David M.,Wilson, Lon J.
, p. 8857 - 8868 (2007/10/03)
Template condensation of 2,2'-diaminobiphenyl, 1,4-bis(2-formylphenyl)-1,4-dithiabutane, and copper(II) tetrafluoroborate yields the new macrocyclic compound [Cu(I)(bite)l(BF4) (bite = biphenyldiimino dithioether). [Cu(I)(bite)]BF4 c
