2576-14-9

Upstream product

• 10467-10-4 ethylmagnesium iodide 
• 55379-74-3 N,N-dimethyl-phenylalanine nitrile 
• 22100-10-3 N-benzyl-N,N-dimethylprop-2-en-1-ylammonium bromide 
• 103-83-3 N,N'-dimethylbenzylamine 
• 123701-37-1 Benzyl-dimethyl-(1-trimethylsilanyl-propyl)-ammonium; iodide 
• 91562-51-5 Dimethyl(α-benzyl)allylamine 

Relevant academic research and scientific papers

Chemical Behavior of N-Alkyl-N-methylbenzylammonium N-Alkylide

N-Alkyl-N-methyl(4-substituted benzyl)ammonium N-alkylides (3), produced by fluoride ion induced desilylation of N-alkyl-N-methyl-N-(4-substituted benzyl)-1-(trimethylsilyl)alkylammonium iodides (2), were mainly converted into N-alkyl-N-methyl-1-(4-substituted benzyl)alkylamines (5, Stevens rearrangement products) and 4-substituted toluenes (8).Both compounds were produced via radical-forming and -destroying pathways from 2-substituted-6--5-methylene-1,3-cylohexadienes (4), which were initially formed from 3 by sigmatropic rearrangement.There is no direct migration pathway from 3 to 5.