257627-65-9

Upstream product

• 101150-39-4 E-1-iodo-1-(dimethylphenylsilyl)propene 
• 1026453-73-5 (E)-(S)-4-(tert-Butyl-diphenyl-silanyloxy)-1-(dimethyl-phenyl-silanyl)-2,3-dimethyl-pent-1-en-3-ol 

Downstream Products

• 257627-69-3 (2S,3S,4S,5R)-1-[5-((tert-butyldiphenylsiloxy)methyl)-4-(dimethylphenylsilyl)-2,3,5-trimethyltetrahydrofuran-3-yl]ethanone 
• 257627-68-2 (S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-4-[(E)-2-(dimethyl-phenyl-silanyl)-1-methyl-vinyl]-2,4,5-trimethyl-[1,3]dioxolane 
• 257627-70-6 (2S,3S,4S,5R)-1-(4-dimethylphenylsilyl-5-hydroxymethyl-2,3,5-trimethyltetra-hydrofuran-3-yl)ethanone 
• 257627-66-0 (2S,3RS)-{[2,3-dimethyl-3,4-bis(trimethylsiloxy)-(E)-pent-1-enyl]-dimethylsilanyl}benzene 

Relevant academic research and scientific papers

Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral.

[reaction: see text] The condensation of allylic diols with unsymmetrical ketones proceeds with high stereoselection to form 2,2-disubstituted 4-acyltetrahydrofurans when the alpha-substituents of the ketone differ substantially in size. A Prins-pinacol c