257862-04-7Relevant articles and documents
An Efficient Synthesis of 4-Halo-5-hydroxyfuran-2(5H)-ones via the Sequential Halolactonization and γ-Hydroxylation of 4-Aryl-2, 3-alkadienoic Acids
Ma, Shengming,Wu, Bin,Shi, Zhangjie
, p. 1429 - 1431 (2004)
4-Halo-5-hydroxyfuran-2(5H)-ones were synthesized via the efficient sequential halolactonization-hydroxylation reaction of 4-aryl-2,3-allenoic acids with I2 or CuX2 (X = Br or Cl) in moderate to good yields. The structures of the pro
Ferric chloride hexahydrate-catalyzed highly regio- And stereoselective conjugate addition reaction of 2,3-allenoates with grignard reagents: An efficient synthesis of β,γ-alkenoates
Chai, Guobi,Lu, Zhan,Fu, Chunling,Ma, Shengming
supporting information; experimental part, p. 1946 - 1954 (2011/02/26)
Ferric chloride hexahydrate was shown to be an efficient catalyst for the conjugate addition of 2,3-allenoates with alkyl-, aryl-, or vinyl-Grignard reagents to synthesize polysubstituted β,γ-unsaturated alkenoates with high regio- and stereoselectivity.