257906-20-0

Basic information

• Product Name: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)] benzene solvate
• CAS NO: 257906-20-0
• Molecular Weight: 868.312
• Mol File: 257906-20-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)] benzene solvate(CAS DataBase Reference)
• NIST Chemistry Reference: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)] benzene solvate(257906-20-0)
• EPA Substance Registry System: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)] benzene solvate(257906-20-0)

Safety Data

• Hazardous Substances Data: 257906-20-0(Hazardous Substances Data)

Upstream product

• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 7647-15-6 sodium bromide 

Relevant articles and documents

Di-μ-bromo-bis[bromo(η6-para-cymene)-ruthenium(II)] benzene solvate and di-μ-iodo-bis[(η6-para-cymene)iodo-ruthenium(II)] toluene solvate

The homologous title molecules, [Ru2Br4(C10H14) 2]·-C6H6, (1), and [Ru2I4(C10H14) 2]·C7H8, (2), consist of arene-ruthenium moieties [Ru-to-ring distances of 1.655 (2) A in (1) and 1.673 (3) A in (2)] with a terminal halogen ligand [Ru - Br 2.548 (1) A in (1) and Ru - I 2.726 (1) A in (2)], held together by two symmetrical halogen bridges [Ru - Br 2.575 (1) A in (1) and Ru - I 2.736 (1) A in (2)]. The arene rings are planar and parallel to each other, and the terminal halogen ligands are coordinated to ruthenium trans with respect to each other. Both molecules possess Ci symmetry.