25825-31-4Relevant academic research and scientific papers
Redox-active metal(II) complexes of sterically hindered phenolic ligands: Antibacterial activity and reduction of cytochrome c. Part III. Copper(II) complexes of cycloaminomethyl derivatives of o-diphenols
Loginova,Gres,Polozov,Koval'Chuk,Osipovich,Zheldakova,Faletrov,Strakha,Azarko
, p. 39 - 46 (2013/07/19)
Redox-active copper(II) complexes of sterically hindered phenolic ligands have been synthesized using 5-tert-butyl-3-(pyrrolidinomethyl)-1,2- dihydroxybenzene (HLI), 5-tert-butyl-3-(piperidinomethyl)-1,2- dihydroxybenzene (HLII), 5-t
Synthesis of linear oligo(catechol) ligands for the metal directed self-assembling of helicates
Albrecht, Markus
, p. 230 - 236 (2007/10/03)
The synthesis of the oligo(catechol) systems 1-4 with different substituents, length of the connecting spacer, and number of catechol units is achieved by the use of various coupling reactions (e.g. Wurtz, Glaser-Eglinton, Stephens-Castro). In order to do this methods of preparing the building blocks, 2,3-dimethoxybenzyl bromides 5, 2,3-dimethoxyphenylacetylene (17), or 1,4-dibromo-2,3-dimethoxybenzene (23) have been developed starting with simple catechol (benzene-1,2-diol) derivatives.
