258267-27-5Relevant academic research and scientific papers
4,4-Dimethyl-4,5-dihydro-1,2-dithiolo-[3,4-c]quinoline-1-thiones in 1,3-dipolar cycloaddition reactions with acetylenic dipolarophiles
Shikhaliev,Medvedeva,Ermolova,Shatalov
, p. 587 - 591 (1999)
The behavior of 4,4-dimethyl-4,5-dihydro-1,2-dithiolo[3,4-c]quinoline-1-thiones in the 1,3-dipolar cycloaddition reaction with acetylenic dipolarophiles has been studied. The rate of cycloaddition is reduced along with the decrease of electron-deficiency of the triple bond. Substituted 4-(1′,3′-dithiol-2′-ylidene)-1,2-dihydroquinoline-3-thiones were shown to be the reaction products. On using a twofold excess of acetylenedicarboxylic acid dimethyl ester, adducts of composition 1 : 2 were formed which occured to be substituted 1′,3′-dithiole-2′-spiro-1-(5,6-dihydrothiino[2,3-c]quinolines) . 1999 KluwerAcademic/Plenum Publishers.
