258355-61-2Relevant academic research and scientific papers
The electrophilic behavior of stable phosphanylcarbenes towards phosphorus lone pairs
Goumri-Magnet, Stéphanie,Polishchuk, Orest,Gornitzka, Heinz,Marsden, Colin J.,Baceiredo, Antoine,Bertrand, Guy
, p. 3727 - 3729 (2007/10/03)
As expected for a singlet carbene, the stable phosphanylsilylcarbene 1 possesses an accessible vacant orbital, as shown by reactions with Lewis bases such as phosphanes and a bimetallic complex containing a side-on- coordinated P?P moiety (see the reactio
